A flexible porous Cu(II) bis-imidazolate framework with ultrahigh concentration of active sites for efficient and recyclable CO2 capture.
نویسندگان
چکیده
By virtue of planar Cu2(μ-OH)2(2+) cluster units, a flexible porous metal azolate framework not only adsorbs large amounts of CO2 (19.6 wt% or 266 g L(-1) at 298 K and 1 atm) with a high zero-coverage adsorption enthalpy (-47 kJ mol(-1)), but also desorbs quickly at very low temperatures.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 100 شماره
صفحات -
تاریخ انتشار 2013